Video: Acid Halides to Ketones: Gilman Reagent
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Video: Acid Halides to Ketones: Gilman Reagent
4.1K Views. Lithium dialkyl cuprate, also known as Gilman reagents, selectively reduces acid halides to ketones. The acid chloride is treated with Gilman reagent at −78 °C in the presence of ether solution to produce a ketone in good yield. As shown below, the mechanism proceeds in two steps. First, one of the alkyl groups of the reagent ...
4.1K views9 months ago
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